尿素醇解合成碳酸酯类化合物技术进展

综述了用尿素醇解合成碳酸酯类化合物的技术进展 ,重点介绍尿素醇解合成碳酸二甲酯研究现状以及与其它工艺路线的比较 ,另外也介绍了尿素醇解合成长碳链脂肪族和芳香族类碳酸酯的研究进展。     

浅谈“水源空调“在丹东市的推广使用

本文通过对“水源空调”的介绍,结合丹东市的地质情况,分析论证其在我市推广使用的可行性。     

省煤器管开裂原因分析

对省煤器开裂管进行了化学成分及宏、微观分析。分析结果表明，在高温高压条件下，在其焊缝溶合区出现粗大的魏氏组织，管材中的珠光体组织产生了不同程度的球化，而母材组织又存在严重的带状组织。在过热条件下熔合区极易出现裂纹，并由此快速扩展，造成省煤器管开裂。     

Design consideration of photocatalytic oxidation reactors using TiO2-coated foam nickels for degrading indoor gaseous formaldehyde

In the design process of the photocatalytic oxidation (PCO) reactor using TiO₂-coated foam nickels, the optimum of catalyst film thickness, light intensity and flow velocity were considered. A model was developed to study the effect of catalyst film thickness on photocatalytic degradation of formaldehyde by a TiO₂-coated foam nickel at continuous flow mode. In this model, external mass transfer and internal molecule diffusion-reaction were considered. A first-order kinetics equation was used to account for the photocatalytic reaction. Two exponential equations were employed to describe the distribution of light intensities in foam nickels and catalyst films, respectively. Validated with experimental data, the model can be used to predict the optimal thickness of catalyst films. A method for determining appropriate light intensities was proposed and discussed. The appropriate light intensity can be obtained by giving a margin, regarded as an excess coefficient, to the light intensity calculated based on the assumption of complete use of excited electron–hole pairs. The excess coefficient needs to be determined experimentally. In addition, the optimal flow velocity of PCO reactors could be consistent with the required one by changing the windward area of foam nickels. Based on the theoretical analyses, a novel PCO reactor containing 15 parallel-connected cells was designed. Each reaction cell was composed of an UV lamp and a TiO₂-coated tubular foam nickel. The performance of the reactor was tested by degrading gaseous formaldehyde at an indoor concentration level. The results showed that the reactor had low pressure loss and good degradation capability.     

基于"资产中心"模式的炼油化工企业设备编码体系设计

针对“资产中心”模式对设备管理系统以及设备编码的要求,设计出松耦合的编码体系,并根据炼油化工企业的特点给出了主要的编码结构。解决了编码层次的固化与设备实际层次结构的多样化之间的矛盾,支持“资产中心”模式下设备管理对信息系统功能的需求。     

The thermal behavior of mechanically activated galena by thermogravimetry analysis

The thermal decompositions of mechanically activated and nonactivated galenas were studied by thermogravimetry analysis (TGA) at the heating rate of 10 K min⁻¹ in argon. Results indicate that the initial temperature of thermal decomposition (abbreviated as T _di) in the TGA curves for different galenas decreases gradually with increased grinding time. The specific granulometric surface area (S _G), the structural disorder, and the content of elemental sulfur of mechanically activated galenas were analyzed by an X-ray diffraction (XRD) laser particle-size analyzer, XRD analysis, and the gravimetric method, respectively, which shows that the specific granulometric surface area of mechanically activated galenas remains almost constant after a certain grinding time, but the lattice distortions (ε) rise, the crystallite sizes (D) decrease, and the elemental sulfur contents of mechanically activated galenas increase with increased grinding time. The results imply that the decrease of the initial temperature of thermal decomposition in the TGA curves for mechanically activated galenas is mainly caused by the increase of lattice distortions, and the formation of new dangling bonds resulted from the production of elemental sulfur of mechanically activated galenas with increased grinding time. Finally, the differences in the thermal-decomposition reactivity between nonactivated and mechanically activated galenas were also discussed.     

An Inductively Coupled Lamb Wave Transducer

Wafer-type piezoelectric transducers are effective transducers for the excitation and detection of ultrasonic Lamb waves in plate-like structures. Such transducers are, however, vulnerable to corrosion and physical damage when mounted in exposed locations. In this paper we describe an inductively coupled Lamb wave transducer that eliminates the need for direct electrical connections. Signals are coupled into and out of the transducer using two probe coils. In this paper we explore the operation of inductively coupled transducers both analytically and experimentally. Finite-element analysis is used to determine inductances and the coupling constant, and electrical circuit analysis to determine the transfer function and its dependence on the gap between the probe coils and the transducer. Experiments show that return signals of millivolt amplitude are obtained when the transducer is excited with 10-V amplitude pulses. These transducers are suitable for permanent mounting on structures to be monitored for cracks or flaws     

Study on Adsorption Behavior of Rare Earth Complexes on Nanometer-Size Titanium Dioxide with ICP-AES

Inrecentyears ,rareearthelements (REEs)havebeenwidelyusedinfunctionalmaterials ,cata lystsandotherproductsinindustry ,diagnosisreagentsofmagneticresonanceimaging (MRI)inmedicineandsomefertilizersinagricultureespeciallyinChina .However,asaresultoftheirusage ,moreandmoreREEsaregettingintotheenvironment,andalsointohumanbodyviafoodchain[1,2 ] .Itisnotclearwhetherrareearthelementsareessentialforman ,soitisveryurgenttostudythebiologicaleffectofrareearthelementsinhumanhealthandenvironment .Inthes…     

Preparation of Compound Ultrafine CeO2 by Wet-Solid-Phase Mechanochemical Modification

To satisfy practical requirements from industrial applications, an alternate route for synthesis compound ultrafine CeO2 powders by wet-solid-phase mechanochemical modification using industrial grade hydrated cerium carbonate as raw material was proposed.The effect of modifier reaction percentage, reaction time, calcining temperature and modifier amount on particle size, density, suspensibility, and hardness of compound CeO2 powder was investigated.The phase evolutions of preparation process were characterized by XRD.SEM micrograph of the final product shows that compound CeO2 powders obtained are well-dispersed, spherically-shaped, uniformly-sized and submicron-sized particles.The method is readily available in raw material, low in cost, simple in process, and has great potential for industrialization.The compound CeO2 powders of different physical properties can be synthesized by controlling the above-mentioned influence factors in preparation process.